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NMR Investigations of 170, MS, MMo, and S7Mo in Thiomolybdatcs

P. Kroneck
Fakultät für Biologie der Universität Konstanz
and O. Lutz and A. Nolle
Physikalisches Institut der Universität Tübingen
Z. Naturforsch. 85«, 226—229 (1980);

[received December 24 1979]

NMR investigations of 17 0, ^S, 95 Mo, and 97 Mo have been used to elucidate the existence and the behaviour of the oxothiomolybdate species, Mo04- n S» 2 ~ ( n = 0,1, 2, 3, 4 ) in aqueous solution. Very large chemical shifts and surprisingly narrow lines have been found for these nuclei in the different species.

Introduction